DOI: 10 . The big advantage of nitromethane is that you can get a lot more power from each explosion inside the engine. You can still . Nitromethane carries its own oxygen, so it needs much less atmospheric oxygen to burn. EXPLOSION. SAFETY DATA SHEET Creation Date 26-Sep-2009 Revision Date 24-Dec-2021 Revision Number 8 1. NM was considered safe for a long time, until a railroad tanker car exploded in 1958. The fuel comes with its own oxygen atoms to help it burn. Chem. CAS No: 75-52-5 EC No: 200-876-6 . Date Founded 1860s. Contact of nitromethane with reducing agents, strong bases, amines, heavy metals or their. Nitromethane was developed in 1872 for a variety of chemical uses, including to serve as a solvent in chemical reactions, as a component of detergents, as a stabilizer in chemical compounds and even as fuel for race cars. 120, (21) 10146 (2004). Membership. Although TNT has more velocity, nitromethane is more energetic as an explosive. 4 S. Han, et al. Nitromethane appears as a colorless oily liquid. An enormous explosion at an east China chemical plant has killed 47 people, seriously injured 90 and put another 640 in the hospital. Kinestik (ammonium nitrate/nitromethane), . Storage: Keep away from sources of ignition. A few moments after the fire started, a series of explosions destroyed a large section of the NP plant, sending shrapnel north and east . Heat or shock does not explode unconfined quantities. This lethal downside also caused the deadliest industrial accident in US history. The force created by the explosion was equivalent to a magnitude 2.1 earthquake. The detonation and successive deflagration result in notably enhanced SWs: with 2.8 g EM, the SW amplitude, impulse and energy are respectively increased by 1.7, 2.1, and 7.9 times . Nitromethane - Physico-chemical Properties. Nitroethane is a nitroalkane substituted by nitro group ethane, and it is a tautomer of an aci-nitroethane. While it burns slowly, there is also the danger of explosion when nitro is used. *water marks the beginning of exothermic chemistry First Explosion: intermolecular proton transfer *using density functional molecular dynamic simulations H₂O Second Explosion: Neat nitromethane and mixtures of nitromethane with six different (primary, secondary, tertiary, and di-) amines were shocked to within 12−17 GPa peak pressure using step wave loading. The blast flattened the plant and 16 neighbouring factories, leaving an enormous crater. The Blower difluoro-nitro-methane. This is when small entrained air bubbles compress and superheat with rapid rises in . Born and raised in Washington, D.C., Mr. Klick is a trial lawyer who has been . Practice Areas. fPOISONOUS GASES ARE PRODUCED IN FIRE, including Nitrogen Oxides. J. Phys. Containers may explode when heated. ABSTRACT: Nitromethane (NM) is widely applied in chemical technology as a solvent for extraction, cleaning, and chemical synthesis. Synonyms: nitrocarbol Use: detonating agent, fuel, solvent, gasoline additive Molecular formula: CH3NO2 . Mt. The impact of nitromethane on the explosion characteristics of diethyl ether -aluminium powder mixed fuel in the presence of different ambient factors is studied in a 20 L sphere-shaped explosion . Under full throttle, a Top Fuel Dragster consumes 1-1/2 gallons of Nitro Methane every second! Reactivity Profile. C. 17003-27-9. Nitromethane is a little like gasoline that has been pre-mixed with nitrous oxide. From a standstill . unknown, Baltimore, MD 21220 Effect of diethylenetriamine on the structure of detonation waves in nitromethane. Heating especially when in confined space may result in an explosion. Nitromethane was used primarily as a commercial solvent and wasn't assumed to be explosive, until a tank car explosion in Mount Pulaski, IL on January 22, 1958 that killed two, injured 60 and left thousands homeless. In case of fire and/or explosion do not breathe fumes. "The demethanizer tower, which removes the methane from the compound product for recovery, stood 150 feet high and 20 feet in diameter," Craft said. Solubility in water at 20 °c 9.5% (by volume). Nitromethaneis a FLAMMABLE LIQUID. properties colorless transparent oily liquid with a faint aromatic odor. It has become fairly well known over the last few years that a simple and powerful high explosive can be made by pouring liquid nitromethane into powdered ammonium nitrate or by adding various liquid sensitizers to nitromethane. The theoretical ideal or stoichiometric air/fuel ratio for gasoline is 14.7:1. The explosion devastated This content will become publicly available on Fri Jul 15 00:00:00 EDT 2022. . It can be used as a rocket fuel, as a solvent for nitric acid fiber and . After much testing, it was realized that nitromethane was a more energetic high explosive than TNT, although TNT has a higher velocity of detonation (VoD) and brisance. With the using of a laser interfe. We investigate the detonation kinetics and explosion reaction mechanisms in a variety of sys … Unfortunately, as this knowledge spread, the ready supply of nitromethane dried up. A formulation that rectifies the issues commonly presented in shock-bubble simulations was proposed by Michael and Nikiforakis [].This formulation considers the cavity as an inert phase (phase 1) and the surrounding material as a reacting phase (phase 2) composed of two materials; the reactant nitromethane as material \(\alpha \) and the gaseous products of reaction as material \(\beta \). According to Enginebuildermag, a 55-gallon drum of Nitro Methane costs a whopping $900. Nitromethane has some odd properties, due to the singular weirdness of the nitro group.. Abstract: Two-dimensional, meso-resolved numerical simulations are performed to investigate the complete shock-to-detonation transition (SDT) process in a mixture of liquid nitromethane (NM) and air-filled, circular cavities. Ammonium nitrate is relatively stable under most conditions but explodes violently when it comes in contact with an open flame. Nitromethane carries its own oxygen, so it needs much less atmospheric oxygen to burn. DOE PAGES ® Journal Article: Ethylenediamine Catalyzes Nitromethane Shock-to-Detonation in Two Distinct Ways. Somewhat similar to the peak pressure, the peak combustion temperature increases with the volume fraction of nitromethane in the range of 10-40%, and slightly decreases in 40-50%. Combustion may produce oxides of nitrogen and other irritants and toxic gases. It was not considered volatile in its pure form until the 1950s, when numerous accidents occurred as it was . Eight Employees Killed In Chemical Plant Explosion: On May 1, 1991, at the IMC Fertilizer, Inc., (IMCF)/Angus Chemical Company plant located in Sterlington, LA, a fire occurred in the area of a waste gas vent compressor (RJ-291) in the nitroparaffins (NP) plant. The monster explosion that destroyed a good bit of Beirut was caused by the detonation of more than 2,700 tons of the fertilizer ammonium nitrate - a ghastly amount of one seriously scary chemical. 1.4.2Occupational exposure According to the 1981-83 National Occupational Exposure Survey (NOES, 1999) as many as 135 000 workers in the United States were potentially exposed to nitro- methane (see General Remarks). The environmental regulations actually block and prevent it from happening. There are three main possible causes of nitromethane becoming shock sensitive and they are as follows: The use of hydrazine as an additive, which, be it noted, is barred by regulations in the USA for that very reason. NITROMETHANE: ICSC: 0522 (October 1997) Nitrocarbol: CAS #: 75-52-5: UN #: 1261 EC Number: 200-876-6 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Flammable. Identification Product Name Nitromethane-d3 Cat No. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.) The maximum peak pressure is equal to 0.94 MPa and the minimum peak pressure 0.58 MPa. The maximum peak temperature is 1340 °C and the minimum 860 °C. It also destroyed Texas City in 1947 and the Alfred P. Murrah Federal Building in Oklahoma City in 1995. Steam and air can form explosive mixtures; the explosion limit is 3%~5% (in volume). Add that to compressed fuel and vapor, and your engine will explode into about a million pieces. Nitromethane is a little like gasoline that has been pre-mixed with nitrous oxide. One of the most insane facts about dragsters is their neck-breaking speed. A Top Fuel dragster can reach 335 mph at top speed and make a thousand-foot run in just 3.62 seconds. Timothy James McVeigh (April 23, 1968 - June 11, 2001) was an American domestic terrorist responsible for the 1995 Oklahoma City bombing that killed 168 people, 19 of whom were children, and injured more than 680 others, and destroyed one third of the Alfred P. Murrah Federal Building. On May 1, 1991, at the IMC Fertilizer, Inc., (IMCF)/Angus Chemical Company plant located in Sterlington, LA, a fire occurred in the area of a waste gas vent compressor (RJ-291) in the nitroparaffins (NP) plant. While Rev. These include mandatory use of blast containment bunkers, detonation traps on all lines, use of pressure relief devices on any portion of a NM line that could be valved off and entrap NM, utilization of fixed deluge and/or water spray system on . Oddly enough, midget and drag racers knew of the explosive properties of Nitro in the late 1940s. At the Texas fertilizer plant, something else served as a fuel: firefighters responded to a fire on the premises at around 7:30. It was not considered volatile in its pure form until the 1950s, when numerous accidents occurred as it was . . Experiments were performed in an effort to elucidate the cause of the explosion. The footage of the mammoth fireball and the effects from the pressure wave are among the most compelling things we have ever seen. We have some confirmed injuries that are being taken to hospitals,'' said Sgt. Particularly, it is shown that the time delay to the appearance of a detonation front in the nitromethane can be reduced from 18 ..mu..sec to less than one ..mu..sec with 0 to 5% DETA, and it was also seen that an ''overdriven'' detonation velocity was measured in the solutions containing from 0.02 to 0.1% DETA. Risk of fire and explosion on contact with incompatible substances. Physical data "The explosion . Lower explosion limit 7.3% in air Hawley's Condensed Chemical Dictionary 15th Edition The shock-induced initiation behaviors resulting from the cases with neat NM, NM with an array of regularly spaced cavities, and NM with randomly distributed cavities are . Nitromethane. People also ask, Is a helmet required for drag racing? Gives off irritating or toxic fumes (or gases) in a fire. nitromethane with reducing agents, strong bases, amines, heavy metals or their oxides, especially at elevated temperatures or in confined spaces - explosion may result. Nitroethane however, has a lower explosive limit of 3.4% by volume in air and is less of an explosive hazard than nitromethane and tetranitromethane. They never repaired and started back up. 50% more volume of fuel compared to gasoline (price would need to be 2/3 of gasoline to . Conditions. To this end, we perform two- and three-dimensional numerical simulations of shock-induced single gas-cavity . An explosion that occurred during a nitromethane rectification process is investigated. If the name sounds familiar it's because the chemical is notorious. Still, the explosiveness of nitromethane was discovered by accident, as this drag-racing site notes: Joe Fette, a former vice president and general manager of Angus Chemical, worked intimately with. Pulaski, Il explosion in late 1950's. Posted by MP173 on Wednesday, December 20, 2006 10:58 PM . That means, 14.7 pounds of air . The use of caustic soda or any other alkaline, used for cleaning out a tank or fuel lines. The force created by the explosion was equivalent to a magnitude 2.1 earthquake. Fizzie vs Massive ExplosionDitch the hipsterbucks and get your Black Rifle Coffee here:https://brcc.coffee/2rjdvS5Click here to subscribe:http://goo.gl/mZDvQ. An explosion that occurred during a nitromethane rectification process is investigated. Power output each stroke increases as a consequence. Anhydrous salts of nitromethane may explode. The Tannerite 2 Case Special is the company's most popular order and has 20 pounds of explosives (40 half-pound . 1-fluoro-1-nitro-ethane. Another issue is solubility. The results of the experimental determination of the detonation parameters of nitromethane (NM) with diethylenetriamine (DETA) solution are presented in this work. STERLINGTON, La. Company employs strict control on all process vessels and equipment that are in nitromethane service. Special Remarks on Explosion Hazards: Warning! The main objective is to understand the origin of localised temperature peaks (hot spots) which play a leading order role at the early stages of ignition. Though Nitro Methane is an incredibly powerful fuel to power an engine, it is expensive to run on. This lethal downside also caused the deadliest industrial accident in US history. The Mt. Explosive decomposition begins at 599 deg F (315 deg C). About Press Copyright Contact us Creators Advertise Developers Terms Privacy Policy & Safety How YouTube works Test new features Press Copyright Contact us Creators . If heating may cause an explosion. This work is concerned with the effect of cavity collapse in non-ideal explosives as a means of controlling their sensitivity. Sterlington, LA. Advertisement. Ethylenediamine Catalyzes Nitromethane Shock-to-Detonation in Two Distinct Ways. Nitromethane was developed in 1872 for a variety of chemical uses, including to serve as a solvent in chemical reactions, as a component of detergents, as a stabilizer in chemical compounds and even as fuel for race cars. Vapour/air mixtures are explosive. Harris was pastor in 1929, the church burned down. via autowise. "Car GATX 29633 was loaded with approximately 10,000 gallons of nitromethane on May 28, 1958, at the Commercial Solvents Corporation plant at Sterlington, La., on the Missouri Pacific Railroad, and was delivered to the Alton and Southern . Combustion, Explosion, and Shock Waves 2013, 49 (4) , 478-483. The monster explosion that destroyed a good bit of Beirut was caused by the detonation of more than 2,700 tons of the fertilizer ammonium nitrate - a ghastly amount of one seriously scary chemical. The explosion force from 100% nitromethane compressed in an engine cylinder to the thickness of, oh say ¾ of an inch, with an added small spark, is about 750amps. A few moments after the fire started, a series of explosions destroyed a large . Nitromethane is not known to occur as a natural product. Nitromethane. The Oklahoma City bombing was a domestic terrorist truck bombing of the Alfred P. Murrah Federal Building in Oklahoma City, Oklahoma, United States, on April 19, 1995.Perpetrated by two anti-government extremists with white supremacist, right-wing terrorist sympathies, Timothy McVeigh and Terry Nichols, the bombing happened at 9:02 a.m. and killed at least 168 people, injured more than 680 . Liquid nitromethane (CH 3 NO 2 —NM) is an important explosive material because of its chemical and physical simplicity. Nitromethane has the benefit of generating far more power with each engine explosion. The electron-withdrawing nature of the group makes it a decent acid; in neutral (i.e., pH 7) water, about 1 . The one factory in the USA left that used to make nitromethane shut down after a chemical fire and explosion. That's the same voltage used in welding sky scrapers together! NM was considered safe for a long time, until a railroad tanker car exploded in 1958. The fuel comes with its own oxygen atoms to help it burn. The videos and story surrounding the latest industrial calamity in China, forever known now as the Tainjin Port Explosion verge on the unbelievable. Two-Stage Explosion in Liquid Nitromethane M. R. Manaa, et al. Sinai church was established in the 1860s. May violently decompose if intensely heated when contaminated. This exothermal reaction produces four nitroalkanes of industrial significance: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. methanol has a fire and explosion risk (probably slightly higher than gasoline, but the clear flame poses an extra danger), requires approx. The Nitro Circus Offers you the chance to view some of the NHRA's greatest racing Grudge matches,. According to IMC officials, a faulty compressor was responsible for initiating the explosion, which involved nitromethane. Published Works. Photo credit: hotrod.com. That means, 14.7 pounds of air . An explosion at a chemical plant that took place March 21 in China's eastern Jiangsu province has killed 78 people (link in Chinese) as of Monday (March 25), and injured more than 600, state . Ammonium nitrate is relatively stable under most conditions but explodes violently when it comes in contact with an open flame. If you like small explosions, then you'll really like the big explosion! (AP) _ An explosion at a fertilizer plant rocked this rural northeast Louisiana town Wednesday afternoon, releasing toxic ammonia gas and prompting an evacuation of all 1,500 residents. Jim Klick was a partner of Herman, Herman & Katz L.L.C., as well as the national firm of Herman Gerel, LLP, and he is now Of Counsel. . B. We have experimentally investigated some of the effects on its properties due to replacing one of its hydrogen atoms with bromine (BrNM) and all its hydrogen atoms with deuterium (DNM). Because explosions could result under conditions of confinement or contamination with other materials, safe handling procedures have been . That seems to be the calling card of several buffoons who have recorded their activities for posterity. Full Record; . To prevent serious corrosion, a thorough flushing of the fuel system and motor is necessary after use. Details of the supplier of the safety data . fDO NOT use dry chemical extinguishers on a fire. Vapors may travel to source of ignition and flash back. 1.4.3Environmental occurrence 8 Nitromethane. Explosion Limits Upper62% Lower7.3% Sensitivity to Mechanical ImpactNo information available Sensitivity to Static DischargeNo information available Specific Hazards Arising from the Chemical Flammable. Expired - Lifetime Application number US605747A Inventor Edgar A Laurence If you are running methanol, there is no problem as nitromethane and methanol mix freely. If the name sounds familiar it's because the chemical is notorious. nitromethane explosive amine volume mixture Prior art date 1945-07-18 Legal status (The legal status is an assumption and is not a legal conclusion. Blast in industrial park in Yancheng. Nitromethane was not known to be a high explosive until a railroad tanker car loaded with it exploded on June 1, 1958. fUse CO 2, water spray or alcohol-resistant foam as extinguishing agents. Nitromethane, the source of the explosion, is sensitive to shock, friction, concussion or heating. The big advantage of nitromethane is that you can get a lot more power from each explosion inside the engine. 115, 6534-6540 (2011). This chemical is harmful if swallowed. See Chemical . We investigate the detonation kinetics and explosion reaction mechanisms in a variety of systems consisting of NM, molecular . It would be nigh impossible to build a new nitromethane manufacturing plant in the USA. Pure nitromethane is an insensitive explosive with a VoD of approximately 6200 m/s, but even so inhibitors may be used to reduce the hazards. Explosion and Renovation Project At 1:10 p.m. on May 1, 1991, an explosion occurred in the NP plant, beginning on the east and north sides of the control station. Closed containers may rupture violently when heated. The process consists in diluting a quantity of nitromethane, CH3NO2, with ether and treating the liquid with a solution of sodium in alcohol, when the sodium compound is precipitated. On a nitromethane explosion cool, dry, well-ventilated area away from incompatible substances - Assignment Point < /a nitromethane! It burns slowly, there is no problem as nitromethane and methanol mix freely a little like gasoline has. In 1935 its pure form until the 1950s, when numerous accidents as. Burned down being taken to hospitals, & # x27 ; s the voltage! Also destroyed Texas City in 1995 10:58 PM sounds familiar it & # x27 ; s the! 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